Archived
This content is available here strictly for research, reference, and/or recordkeeping and as such it may not be fully accessible. If you work or study at University of Kentucky and would like to request an accessible version, please use the SensusAccess Document Converter.
Date Available
12-7-2011
Year of Publication
2005
Document Type
Thesis
College
Engineering
Department/School/Program
Electrical Engineering
Faculty
Vijay P. Singh
Abstract
In this work, organic solar cells of the configuration ITO/Pedot:PSS/CuPc/PTCBI/Al (Indium tin oxide/poly(3,4-ethylenedioxythiophene): polystyrene sulfonic acid/copper phthalocyanine/3,4,9,10-perylenetetracarboxylic bisbenzimidazole/aluminum) were investigated. A high open-circuit voltage (Voc) of 1.15 V was obtained when the PTCBI layer was 7 nm thick. Lower Voc values were observed for the same structure with silver, copper and gold electrodes instead of aluminum. However, short-circuit current density (Jsc) with these electrodes was much higher (4 mA/cm2) than in the case of aluminum (0.12 mA/cm2). Results were interpreted in terms of a modified CuPc/Al Schottky diode for the thin PTCBI case and a CuPc/PTCBI heterojunction for the thick PTCBI case. Also, the formation of a thin, protective aluminum oxide layer under the aluminum electrode was postulated. For devices with silver, copper and gold electrodes, absence of this protective layer was thought to be the cause of a relatively lower Voc and higher Jsc.
Recommended Citation
Parthasarathy, Balaji, "FABRICATION AND CHARACTERIZATION OF CuPc BASED ORGANIC SOLAR CELLS" (2005). University of Kentucky Master's Theses. 265.
https://uknowledge.uky.edu/gradschool_theses/265
